Silver-promoted desilylation catalyzed by ortho- and allosteric cucurbiturils
Cucurbit[6]-, [7]-, and [8]uril can catalyze the silver(I)-promoted desilylation of trimethylsilylalkynyl-containing pseudorotaxanes by stabilizing a key π-alkynyl silver intermediate through favorable interactions between the metallic cation and the cavi
Lu, Xiaoyong,Masson, Eric
supporting information; experimental part
p. 2310 - 2313
(2010/08/04)
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