- Synthesis of boron-substituted diaryliodonium salts and selective transformation into functionalized aryl boronates
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Dormant boron awaits its true destiny in diaryliodonium salts synthesized from aryl boronate derivatives according to two alternative general methods with hypervalent iodine(III) reagents and fluoroalcohol solvents: transformation of an aryl C-H bond and
- Ito, Motoki,Itani, Itsuki,Toyoda, Yosuke,Morimoto, Koji,Dohi, Toshifumi,Kita, Yasuyuki
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supporting information
p. 12555 - 12558
(2013/02/22)
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- Fluoroalcohols: Versatile solvents in hypervalent iodine chemistry and syntheses of diaryliodonium(III) salts
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We first introduced 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) and 2,2,2-trifluoroethanol (TFE) as unique solvents for reactions involving hypervalent iodine-mediated phenolic oxidations in the 1980s, in which the fluoroalcohols have been successfully utili
- Dohi, Toshifumi,Yamaoka, Nobutaka,Kita, Yasuyuki
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experimental part
p. 5775 - 5785
(2010/09/14)
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