Enantiomerically divergent pathways in Tsuji-Trost reactions: exploiting the structural differences between β-acyloxy-o-(diphenylphosphino)benzamides and β-amido-o-(diphenylphosphino)benzoates
Using a single chiral scaffold, (1R,2S)-norephedrine, a series of monophosphine ligands have been prepared. The ligands prepared, β-acyloxy-(o-diphenylphosphino)amides and β-amido-(o-diphenylphosphino)esters, give rise to enantiomerically divergent produc
Nelson, Brandon M.,Chavda, Mihir K.,Oliphant, Jonathan,King, Jalisa M.,Szczepura, Lisa F.,Hitchcock, Shawn R.
p. 1075 - 1080
(2016/10/11)
THERMAL CYCLIZATION OF Β-HYDROXYAMIDES TO OXAZOLINES
Thermal conversion of amides derived from erythro and threo ephedrines yields stereospecific oxazolines.
Somanathan, Ratnasamy,Aguilar, Hugo R.,Rivero, Ignacio A.,Aguirre, Gerardo,Hellberg, Lars H.,Yu, Zheng,Thomas, Jacquelin A.
p. 348 - 353
(2007/10/03)
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