- Effect of substituents on the aggregate structure and photovoltaic property of violanthrone derivatives
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In this paper, three violanthrone derivatives with different substituents, 16,17-bis(2-ethylhexyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione (3), 16,17-bis(octyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione (4), 16,17-bis(hexyloxy)-anthra[9,1,2-cde-]benzo[rst]pentaphene-5,10-dione (5), are synthesized. It is found that the substituent has a great effect on the aggregate structures of violanthrone derivatives: the shorter the side chain is, the stronger the intermolecular π-π actions in the solid state is. Because all compounds are p-type semiconductive materials with the relatively low-lying highest occupied molecular orbital (HOMO) energy levels (~-5.1 eV) and low band gaps (~1.8 eV), their photovoltaic properties are evaluated when the blends of violanthrone derivatives and [6,6]-phenyl-C 61-butyric acid methyl ester (PCBM) (1:1, w/w) are used as the active layers of organic solar cells. Among three violanthrone derivatives, compound 5 exhibits the best photovoltaic performance with the power conversion efficiency (PCE) of 0.54% since the aggregate structure of compound 5 is in favor of charge transport.
- Shi, Minmin,Hao, Feng,Zuo, Lijian,Chen, Yi,Nan, Yaxiong,Chen, Hongzheng
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- A 16, 17-double-alkoxy Anthracyclinone purple method for preparing derivatives of
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The invention discloses a method for preparing 16,17-dialkoxyviolanthrone derivatives. A readily available 16,17-dimethoxyviolanthrone dye is used as an initial raw material, a 16,17-dihydroxyviolanthrone intermediate is prepared through demethylation, and the corresponding 16,17-dialkoxyviolanthrone derivatives are synthesized through Williamson ether synthesis reaction. The method has the characteristics of short whole reaction route, high yield, mild reaction conditions and low cost.
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Paragraph 0028; 0029; 0030; 0031; 0032
(2016/12/01)
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