2,3-Dihydro-3-oxo-2-phenyliodonium-benzo[b]thiolenide-1,1-dioxide: Synthesis, decomposition and Cu-catalyzed thermal reactions.
Iodonium ylide 4 was prepared in 93% yield from the reaction of β-ketosulfone 3 with phenyl iodosyl bis(trifluoroacetate). Although insoluble in most solvents, ylide 4 was readily soluble in a mixture of CH2Cl2 ! ethanol (1:1), yield
Hadjiarapoglou, Lazaros P.,Schank, Kurt
p. 9365 - 9376
(2007/10/03)
Reactions of 2,3-dihydro-2-phenyliodonium-3-oxo-benzo[b]thiolenide-1,1-dioxide
2,3-Dihydro-2-phenyliodonium-3-oxo-benzo[b]thiolenide-1,1-dioxide was found to react with various substrates like alkenes, alkynes, thiobenzophenones et.
Hadjiarapoglou,Schank
p. 6673 - 6676
(2007/10/02)
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