Migration of a Benzyl group in the Lossen-like Rearrangement of an N-Phosphinoyl-O-sulphonylhydroxylamine
Migration of a group other than aryl has been observed for the first time in the Lossen-like rearrangement of an N-phosphinoyl-O-sulphonylhydroxylamine: the benzylic substrate (ArCH2)2P(O)NHOMs (Ar= p-tolyl) gives the phosphonamidate ArCH2P(O)(OR)NHCH2Ar
Harger, Martin J. P.,Smith, Adrian
p. 1447 - 1451
(2007/10/02)
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