- Syntheses and Characterization of Stable Pseudo-octahedral Tris-phenolato Complexes of Vanadium-(III), -(IV), and -(V)
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Reaction of the anionic form of the hexadentate ligand 1,4,7-tris(5-t-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L) with VCl3 in MeCN affords LVIII which is oxidized chemically and electrochemically to IV>(1+) and V>(2+); electrochemical, magnetic, and electronic spectroscopic properties of these complexes and the X-ray structure of are reported.
- Auerbach, Ulf,Della Vedova, Beatrice S. P. C.,Wieghardt, Karl,Nuber, Bernhard,Weiss, Johannes
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