α-FLUORO- AND α,α-DIFLUOROALKANALS BY SUBSTITUTION OF VICINAL BROMOFLUOROALKANES AND SUBSEQUENT PUMMERER REARRANGEMENT
2-Fluoro- or 2,2-difluoro-1-bromoalkanes readily ondergo nucleophilic substitution by sodium thiophenolate to give 2-fluoro- or 2,2-difluoroalkyl phenyl sulfides (1a-1c).The latter may be oxidized to the corresponding sulfoxides (2a-2c).Heating with aceti
Suga, Hiroaki,Schlosser, Manfred
p. 4261 - 4264
(2007/10/02)
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