Use of the Mitsunobu reaction in the synthesis of polyamines
The Mitsunobu reaction has been used in the synthesis of polyamine analogues. The synthesis of the (R,R), (S,S) and meso-isomers of a tetraamine are described. The chemistry was used to synthesize a fluorinated polyamine analog and a hexaamine.
Edwards, Michael L.,Stemerick, David M.,McCarthy, James R.
p. 5579 - 5590
(2007/10/02)
Stereospecific synthesis of secondary amines by the Mitsunobu reaction
A facile synthesis of secondary amines from alcohols is reported with N-methyltrifluoromethanesulfonamide (2) in the Mitsunobu reaction. The reaction was demonstrated to proceed with inversion of configuration and provided a convenient synthetic route to
Edwards,Stemerick,McCarthy
p. 3417 - 3420
(2007/10/02)
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