Synthesis and Characterization of Four Diastereomers of Monorhamnolipids
Rhamnolipids are amphiphilic glycolipids biosynthesized by bacteria that, due to their low toxicity and biodegradability, are potential replacements for synthetic surfactants. The previously limited access to pure materials at the gram scale has hindered
Palos Pacheco, Ricardo,Eismin, Ryan J.,Coss, Clifford S.,Wang, Hui,Maier, Raina M.,Polt, Robin,Pemberton, Jeanne E.
p. 5125 - 5132
(2017/05/04)
Stereocontrolled Reduction of β-ketoesters by Geotrichum candidum. Preparation of D-3-hydroxyalkanoates
Geotrichum candidum has been used for the preparative reduction of β-oxoalkanoic esters to the corresponding D-β-hydroxyesters.The stereospecificity for ethyl 3-oxobutanoate or 3-oxopentanoate is markedly increased by preincubation of the mycelium before addition of the substrate. Keywords: microbial reduction; Geotrichum candidum; β-ketoesters; D-3-hydroxyalkanoates.
Buisson, Didier,Azerad, Robert,Sanner, Caroline,Larcheveque, Marc
p. 987 - 988
(2007/10/02)
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