- Sulfur oxyfluoride derivatives. III
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The reaction of S2O6F2 with the anions CF3O-, SF5O-, -N(SO2F)2, and (NO2)2CCN- produced the corresponding covale
- Ruff,Merritt
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- Limiting high-pressure rate coefficient for the recombination reaction FSO2 + FSO3 → FS(O2)O(O2)SF: An experimental and theoretical study
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The kinetics of the recombination reaction FSO2 + FSO 3 → FS(O2)O(O2)SF has been studied at 298 K. Both radicals were generated by 193-nm laser flash photolysis of FS(O 2)O(O2)SF at total C
- Tucceri,Croce,Cobos
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- Hydrogen abstraction reactions of peroxydisulfuryl difluoride
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Several new as well as a large number of known fluorosulfate-containing molecules have been synthesized via hydrogen radical abstraction with S2O6F2. In general, the reactions were moderated sufficiently to permit wide applicability of this synthetic approach by dilution of the reactants and by lowering of the temperature. Amine, alcohol, aromatic, aliphatic, perfluoroalkyl, hydrogen halide, and thiol hydrogens were easily abstracted and in most cases converted to stable fluorosulfate products.
- Kirchmeier, Robert L.,Shreeve, Jean'ne M.
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p. 2886 - 2890
(2007/10/05)
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