- A REGIOSPECIFIC SYNTHESIS OF UNSATURATED NUCLEOSIDES, CARBOHYDRATES AND OTHER OLEFINS
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Vicinal disubstituted nucleosides, carbohydrates and cyclohexane derivatives with a pair of radical leaving groups, such as chloro, bromo, phenoxythiocarbonyloxy, and imidazolylthiocarbonyloxy groups, have been successfully converted to the corresponding olefins in high yields (60-90 percent) without observed side products, by reaction with tri-n-butyltin hydride and azobisisobutyronitrile in an appropriate solvent.
- Lin, Tai-Shun,Yang, Jing-Hua,Liu, Mao-Chin,Zhu, Ju-Liang
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p. 3829 - 3832
(2007/10/02)
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