A process is described in which a lactone STR1 is reacted with an alkylester X1 --CH2 and an oxidizing or dehydrogenating agent to form the phenol ester STR2
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(2008/06/13)
A new and versatile route for the synthesis of highly substituted benzenoids
A new route for the synthesis of highly substituted benzenoids has been developed. Key steps include the conversion of unsaturated lactone 7 to carboxy substituted cyclohexenone 8 followed aromatization to give phenol 9. The phenolic functionality provides a handle for further modification to give substituted benzenoids of type 2.
Robl, Jeffrey A.
p. 3421 - 3424
(2007/10/02)
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