Starting from 4-methylcyclohexanone (7), a concise total synthesis of the pinguisane-type sesquiterpenoid acutifolone A, in racemic form, has been accomplished in 14 steps with an overall yield of 14.5%. The Royal Society of Chemistry 2009.
Hsieh, Ming-Tsang,Liu, Hsing-Jang,Ly, Tai Wei,Shia, Kak-Shan
experimental part
p. 3285 - 3290
(2009/10/23)
Total regiospecific synthesis of the selagine tricyclic ring system
Starting from 4-methylcyclohexanone, a total synthesis of the selagine tricyclic ring system is described in which complete control of regiospecificity is achieved in the elaboration of functionality.
Gravel, D.,Bordeleau, L.,Ladouceur, G.,Rancourt, J.,Thoraval, D.
p. 2945 - 2947
(2007/10/02)
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