Photo-Arylation. VII. Photoreaction of 2-Halopyridine with Indole
Photolysis of 2-halopyridine with indole afforded the (2-pyridyl)indoles as a regioisomeric mixture.On the basis of the isomer distributions, an electron transfer mechanism is suggested for the present reaction.The regioselectivity was found to be fairly dependent on the solvent polarity. Keywords---(2-pyridyl)indole; photoarylation; photolysis; 2-halopyridine; indole; electron transfer; solvent effect; isomer distribution
Deoxygenation Reactions of ortho-Nitrostyrenes with Carbon Monoxide Catalysed by Metal Carbonyls: a New Route to Indoles
The metal carbonyls Fe(CO)5, Ru3(CO)12, and Rh6(CO)16 are catalysts for the deoxygenation of ortho-nitrostyrenes under carbon monoxide pressure to give indole derivatives; the crystal structure of a non-catalytically active rhodium complex obtained during the synthesis of (5e) is reported.
Crotti, Corrado,Cenini, Sergio,Rindone, Bruno,Tollari, Stefano,Demartin, Francesco
p. 784 - 786
(2007/10/02)
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