Regioselective Oxidation of Piperidine-3 Derivatives: A Synthetic Route to 2,5-Substituted Piperidines
Mercuric acetate oxidation of 1-benzyl-3,3-(ethylenedioxy)piperidine (1) and of 3-CO2Et- and 3-CH2OH-substituted piperidines 7-9 was shown to occur regioselectively at the 6-position.Trapping of the resulting 6-iminium ions with cyanide yielded the corres
Compernolle, Frans,Saleh, M. Ashty,Branden, Stefan Van den,Toppet, Suzanne,Hoornaert, Georges
p. 2386 - 2390
(2007/10/02)
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