A new protocol for the enantioselective synthesis of methyl-substituted alkanols and their derivatives through a hydroalumination/zirconium-catalyzed alkylalumination tandem process
Methyl-substituted alkanols have been synthesized enantioselectively (90-93% ee) in a one-pot hydroalumination/carboalumination tandem process (see scheme). This enantioselectively represents an increase of about 15% from the previously attainable ee values. DIBAH = diisobutylaluminum hydride, IBAO = isobutylaluminoxane.
Huo, Shouquan,Shi, Ji-Cheng,Negishi, Ei-Ichi
p. 2141 - 2143
(2007/10/03)
CODIMERIZATION OF C6 - C10 α-OLEFINS WITH BUTADIENE USING ZIRCONIUM COMPLEXES
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Vostrikova, O. S.,Ibragimov, A. G.,Tolstikov, G. A.,Zelenova, L. M.,Dzhemilev, U. M.
p. 1132 - 1134
(2007/10/02)
DIMERIZATION AND CODIMERIZATION OF HIGHER α-OLEFINS, CATALYZED BY ZIRCONIUM COMPLEXES
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Vostrikova, O. S.,Ibragimov, A. G.,Tolstikov, G. A.,Zelenova, L. M.,Dzhemilev, U. M.
p. 1638 - 1640
(2007/10/02)
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