Synthesis and Circular Dichroism of Steroids with a 1,4-Benzodioxane Chromophore: on the Absolute Configuration of (-)-Silandrin
Starting from cholesterol the three possible stereoisomeric 1,4-benzodioxanes 24, 31, 32 and a series of analogues with 2βH,3βH configuration (25-27, 29, 30) have been synthesized.The α band of the 1,4-benzodioxane chromophore has been unequivocally ident
Antus, Sandor,Baitz-Gacs, Eszter,Snatzke, Guenther,Toth, Tamas S.
p. 633 - 641
(2007/10/02)
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