Microbial hydroxylation and functionalization of synthetic polycyclic enones
The regio- and stereoselective hydroxylation of variously substituted asymmetric 4a-methyl octalenones by selected fungal strains has been shown to afford, sometimes in high yields, several optically pure derivatives, generally hydroxylated in the B-ring. The potential of this method for the preparation of functionalized (hydroxylated) chiral synthons is evaluated and discussed.
Microbial hydroxylation and functionalization of synthetic bicyclic enones
The regio- and stereoselective hydroxylation of substituted octalones by various fungal strains has been evaluated. Several hydroxylated derivatives have been obtained and the potential of this method for the preparation of useful chiral synthons is discussed.
Hammoumi,Revial,D'Angelo,Girault,Azerad
p. 651 - 654
(2007/10/02)
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