In addition to Diels-Alder and hetero-Diels-Alder reactions, tetrafluoro-o-benzoquinone (o-fluoranil) undergoes nucleophilic additions, addition-eliminations, dioxole formation, and charge-transfer complexation, reacting at every site on the molecular skeleton. It also effects dehydrogenations and other oxidations. The quinone can function as a (CF) 4 synthon.
Kumar, Vivek,Ramanathan, Sudharsanam,Sang, Dayong,Chen, Xuanyi,Lemal, David M.
p. 966 - 970
(2012/03/22)
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