- Efficient coupling of 2-halopyrimidines to 2,2'-bipyrimidines
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2-chloropyrimidine, 2-chloro- and 2-bromo-4,6-dimethylpyrimidines, 2-chloro- and 2-bromo-4,6-diphenylpyrimidines have been dimerized to the corresponding 2,2'-bipyrimidines in good yields by Tiecco's method using NiCl2, triphenylphosphine and zinc in DMF.
- Nasielski,Standaert,Nasielski-Hinkens
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- COMPOUND FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
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Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, fully secured of driving stability, and of simple constitution. Also disclosed is a compound useful for the fabrication of said organic electroluminescent device. This compound for organic electroluminescent device is a bipyrimidyl compound which has a basic skeleton of 2,2'-bipyrimidyl and is substituted by an aromatic hydrocarbon group, an aromatic heterocyclic group, or a substituted amino group. The aforementioned organic electroluminescent device has a light-emitting layer between an anode and a cathode which are piled one upon another on a substrate and the light-emitting layer contains a phosphorescent dopant and the aforementioned bipyrimidyl compound as a host material.
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Page/Page column 14-15
(2010/11/03)
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- Pyrimidine-core extended π-systems: General synthesis and interesting fluorescent properties
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We have developed a simple but powerful synthetic strategy that permits the assembly of π-systems onto a pyrimidine core in a programmable and diversity-oriented format. The nucleophilic addition of ArLi to 2-methylthiopyrimidine, followed by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation, resulted in the production of 4-aryl-2-methylthiopyrimidines. The iterative reaction sequence then gave 4,6-diaryl-2-methylthiopyrimidines. The resulting adduct was further allowed to react with ArMgBr under the catalytic influence of NiCl2(dppe) to afford 2,4,6-triarylpyrimidines. By following this synthetic scheme, interesting pyrimidine-core π-systems were rapidly constructed in a programmable fashion. The successful discovery of a number of interesting fluorescent materials and properties (e.g., solvatofluorochromism) speaks well for the potential of our platform strategy in the development of functional organic materials. Copyright
- Itami, Kenichiro,Yamazaki, Daisuke,Yoshida, Jun-Ichi
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p. 15396 - 15397
(2007/10/03)
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