Exploring the potential of some yeast strains in the stereoselective synthesis of aldol reaction products and its reduced 1,3-dialcohol derivatives
The behavior of two yeast strains has been studied under different conditions. Both microorganims catalyzed the aldol reaction between activated aldehydes and acetone when a large amount of the latter was present in the reaction medium producing, with mod
Andreu, Cecilia,Del Olmo, Marcelli
p. 57 - 61
(2013/06/27)
One-pot chemoenzymatic synthesis of chiral 1,3-diols using an enantioselective aldol reaction with chiral Zn2+ complex catalysts and enzymatic reduction using oxidoreductases with cofactor regeneration
We previously reported on enantioselective aldol reactions of acetone and some aldehydes catalyzed by chiral Zn2+ complexes of L-prolyl-pendant [12]aneN4 (L-ZnL1) and L-valyl-pendant [12]aneN 4 (L-ZnL2/sup
Sequential and modular synthesis of chiral 1,3-diols with two stereogenic centers: Access to all four stereoisomers by combination of organo- and biocatalysis
Chemical Equitation Presentation Biocompatible: A modular chemoenzymatic synthesis (see scheme) based on asymmetric organo- and biocatalytic reaction sequences allows the sequential construction of both stereogenic centers of 1,3-diols and leads to all fo
Baer, Katrin,Krausser, Marina,Burda, Edyta,Hummel, Werner,Berkessel, Albrecht,Groeger, Harald
supporting information; experimental part
p. 9355 - 9358
(2010/03/25)
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