ELECTRONIC MATRIX ISOLATION SPECTROSCOPIC STUDIES OF THE GROUP IIA METAL-WATER PHOTOCHEMISTRY.
Results are reported of an investigation of the electronic structures of the Group IIA metal atom hydration reaction intermediates (M. . . OH//2 adducts) and their subsequent photolysis products (HMOH and MOH). For the adduct, the metal-water interaction is sufficiently strong so as to perturb significantly the electronic structure of the metal atom, which results in a unique band structure for the adduct that is red-shifted from the metal atomic resonance transition. Selective photolysis studies are conducted to assist in deconvoluting the complex band structure of the adduct. Molecular orbital theory is invoked to interpret the nature of the ground and excited states of the adduct.
Douglas,Hauge,Margrave
p. 201 - 235
(2008/10/08)
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