Endothermic formation of a chemical bond by entropic stabilization: Difluoronitroxide radical in solid argon
Difluoronitroxide radical (F2NO) has been formed in solid argon matrices by successive addition of two diffusing F atoms to NO. This radical exists in dynamic equilibrium with a van der Waals complex (FFNO). Measurements of the equilibrium concentrations as a function of temperature show that the changes in enthalpy and the entropy associated with formation of the F2NO radical are ΔH = 1240 ± 180 J/mol and ΔS = 62 ± 10 J/(mol K). Because both these quantities are positive, the equilibrium favors F2NO only at elevated temperatures. This situation is a rare case in which formation of a chemical bond is stabilized only by an increase in the entropy of the system.
Misochko, Eugenii Ya.,Akimov, Alexander V.,Goldschleger, Ilya U.,Boldyrev, Alexander I.,Wight, Charles A.
p. 405 - 410
(2007/10/03)
Oxidative chemical oxygenation of NF3 and novel synthesis of NF3O
-
Christe, Karl O.
p. 6136 - 6137
(2008/10/08)
More Articles about upstream products of 13847-65-9