Palladium-Catalyzed Coupling of Terminal Alkynes to the Free cis-Diol Metabolite Produced from the Oxidation of Bromobenzene by Pseudomonas putida: Synthesis of New Homochiral 3-Alkynyl cis-Cyclohexa-3,5-diene-1,2-diols
The free cis-diol metabolite (1) produced from the oxidation of bromobenzene by Pseudomonas putida underwent Pd(0)-catalyzed coupling with trimethylsilyl acetylene, phenylacetylene and 1-hexyne providing the novel homochiral (1S,2R)-3-alkynyl cis-cyclohex
Hudlicky, Tomas,Boros, Eric E.
p. 217 - 220
(2007/10/02)
Enzymatic and Chemical Syntheses of cis-Dihydrodiol Derivatives of Monocyclic Arenes
Metabolism of bromobenzene and iodobenzene by growing cultures of Pseudomonas putida UV4 gave the corresponding cis-dihydrodiol products 1 and 2 in high yields; subsequent direct chemical substitution of the halogen atoms in these metabolites provided a new range of enantiomerically pure cis-dihydrodiols of known absolute configuration.
Boyd, Derek R.,Hand, Mark V.,Sharma, Narain D.,Chima, Jagdeep,Dalton, Howard,Sheldrake, Gary N.
p. 1630 - 1632
(2007/10/02)
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