Addition of 1,2-dihaloperfluoroalkanes to alkenes initiated by dichlorobis(?-cyclopentadienyl)titanium and iron
Addition of 1,2-dihaloperfluoroalkanes to various alkenes promoted by catalytic amounts of dichlorobis(?-cyclopentadienyl)titanium(IV) Cp2TiCl2 and iron powder gives 1:1 adducts in excellent yields.The reaction is performed in protic solvent (EtOH) withou
Synthesis of Functionalized Organic Molecules containing a Tetrafluoroethylene Fragment by Cobaloxime-Promoted Fluoroalkylation with Substituted Tetrafluoroethyl Bromides
Functionalized organic molecules containing a tetrafluoroethylene fragment have been synthesized in moderate to excellent yields via cobaloxime/Zn-redox-couple-promoted fluoroalkylation of various C-C multiple bonds with a variety of substituted tetrafluo
Hu, Chang-Ming,Qiu, Yao-Ling
p. 331 - 334
(2007/10/02)
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