Electrochemically Oxidative C-C Bond Cleavage of Alkylarenes for Anilines Synthesis
In contrast to the recent breakthrough in electrochemical C-H aminations, the electrochemically oxidative C-N bond formation through a C-C bond cleavage is rarely studied. This work describes an electrochemical C-C amination of alkylarenes for the efficie
Adeli, Yeerlan,Huang, Kaimeng,Liang, Yujie,Jiang, Yangye,Liu, Jianzhong,Song, Song,Zeng, Cheng-Chu,Jiao, Ning
FeCl2-promoted cleavage of the unactivated C-C bond of alkylarenes and polystyrene: Direct synthesis of arylamines
Ironing it out: An efficient and convenient nitrogenation strategy involving C-C bond cleavage for the straightforward synthesis of versatile arylamines is presented. Various alkyl azides and alkylarenes, including the common industrial by-product cumene, react using this protocol. Moreover, this method provides a potential strategy for the degradation of polystyrene. Copyright
Qin, Chong,Shen, Tao,Tang, Conghui,Jiao, Ning
p. 6971 - 6975
(2012/09/25)
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