- A modular and scalable one-pot synthesis of polysubstituted furans
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One four all: Allyl dienol carbonates can be readily converted into diversely substituted furans by a one-pot four-step sequence featuring a palladium-catalyzed decarboxylative allylic alkylation, a microwave-mediated Cope rearrangement, a nucleophilic addition, and a dehydration reaction (see scheme). The protocol is operationally simple, highly flexible, and provides di-, tri-, and tetrasubstituted furans starting from readily available materials. Copyright
- Fournier, Jeremy,Arseniyadis, Stellios,Cossy, Janine
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supporting information; experimental part
p. 7562 - 7566
(2012/10/18)
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