Isocyanide based multicomponent reactions of oxazolidines and related systems
N-Alkyloxazolidines react in a multicomponent reaction with carboxylic acids and isocyanides to give N-acyloxyethylamino acid amides. The previously reported reaction conditions were improved using a design of experiments approach (DoE). Under the optimis
Waller, Robert W.,Diorazio, Louis J.,Taylor, Brian A.,Motherwell, William B.,Sheppard, Tom D.
experimental part
p. 6496 - 6507
(2010/10/03)
Reaction of α-aminoalcohols with α-ketoaldehydes and gem-dihalogenoketones: obtention of α-ketooxazolidines, morpholinones and heterodecalines. X-Ray structure determination of 4,4a,8-trimethyl octahydro-1,4-oxazinooxazine
Aryl and alkylglyoxals react with 2-(methylamino)ethanol 2a affording α-ketooxazolidines 9 which can rearrange into morpholin-2-ones 10.Methylglyoxal leads to 1,4,5,8-heterodecalines, the structure and cis-rings junction of which were proved by X-ray diff
Rouzic, A. le,Duclos, M.,Patin, H.
p. 952 - 961
(2007/10/02)
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