Chemoenzymatic approaches to obtain chiral-centered selenium compounds
The synthesis of chiral-centered selenium compounds is presented. Enantioselective oxidations of these organoselenium compounds were performed using a wide range of biocatalysts, including Baeyer-Villiger monooxygenases, oxidoreductases-containing Aspergillus terreus and lipase (Cal-B) in the presence of oxidants. Finally, efficient synthesis of enantiopure organoselenium compounds using a kinetic resolution approach mediated by Cal-B was achieved.
Brondani, Patricia B.,Guilmoto, Nathalie M. A. F.,Andrade, Leandro H.,Dudek, Hanna M.,Fraaije, Marco W.
p. 10431 - 10436,6
(2012/12/12)
Chemoenzymatic approaches to obtain chiral-centered selenium compounds
The synthesis of chiral-centered selenium compounds is presented. Enantioselective oxidations of these organoselenium compounds were performed using a wide range of biocatalysts, including Baeyer-Villiger monooxygenases, oxidoreductases-containing Aspergillus terreus and lipase (Cal-B) in the presence of oxidants. Finally, efficient synthesis of enantiopure organoselenium compounds using a kinetic resolution approach mediated by Cal-B was achieved.
Brondani, Patrícia B.,Guilmoto, Nathalie M.A.F.,Dudek, Hanna M.,Fraaije, Marco W.,Andrade, Leandro H.
p. 10431 - 10436
(2013/01/15)
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