The development of carbon-carbon bond forming reactions of aminal radicals
Aminal radicals were generated and used in synthetic reactions for the first time. Aminal radicals are formed from aminals by radical translocation using AIBN and a stoichiometric hydrogen atom donor, or by SmI2 reduction of N-acyl amidines or amidinium ions in the presence of a proton source. Aminal radicals were found to participate in inter- and intramolecular C-C bond forming reactions with electron deficient alkenes. Chemical yields were as high as 99%.
Schiedler, David A.,Vellucci, Jessica K.,Lu, Yi,Beaudry, Christopher M.
p. 1448 - 1465
(2015/02/19)
Formation of carbon-carbon bonds using aminal radicals
Aminal radicals were generated by radical translocation processes. For the first time, it is shown that they participate in carbon-carbon bond forming reactions. Either stannane or silane hydrogen atom donors are suitable for the reaction. More than 30 su
Schiedler, David A.,Vellucci, Jessica K.,Beaudry, Christopher M.
p. 6092 - 6095
(2013/02/23)
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