Markovnikov-selective hydrothiolation of styrenes: Application to the synthesis of stereodefined trisubstituted olefins
BT-sulfones react with aromatic aldehydes to furnish trisubstituted alkenes with excellent Z stereoselectivity. These sulfones are synthesized by hydrothiolation of styrene and styrenyl derivatives (followed by oxidation). This method provides a conceptually novel way to prepare these important sulfur compounds.
Savolainen, Markku A.,Wu, Jimmy
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p. 3802 - 3804
(2013/08/23)
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