The invention of radical reactions. Part XXIV. Relative rates of acylation and radical deoxygenation of secondary alcohols
Secondary alcohols were transformed into various thiocarbonyl derivatives. Reduction of these compounds using tributyltin hydride and an initiator afforded the corresponding deoxy-compounds. Half-life and competitive measurements showed that all these reactions were fast and could be run to completion.
Barton,Dorchak,Jaszberenyi
p. 7435 - 7446
(2007/10/02)
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