A NOVEL REARRANGEMENT OF TERTIARY α-ALLENIC ALCOHOL CARBAMATES. PREPARATION OF 2-O-CARBAMOYL-4,4-DISUBSTITUTED-1,3-BUTADIENES
Treatment of a variety of tertiary α-allenic alcohols with N-tosyl isocyanate results in a facile and novel rearrangement reaction that provides isolable 2-O-carbamoyl-4,4-disubstituted-1,3-butadienes in a stereoselective manner.
Friesen, Richard W.,Kolaczewska, Aleksandra E.,Khazanovich, Nina
p. 6715 - 6718
(2007/10/02)
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