cas 145545-43-3, TERT-BUTYLDIPHENYLSILYL CYANIDE | Articles data ｜lookchem

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145545-43-3

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Addition of tert-Butyldimethyl- or tert-Butyldiphenylsilyl Cyanide to Hindered Ketones
The addition of trimethylsilyl cyanide (TMSCN), tert-butyldimethylsilyl cyanide (TBDMSCN) or tert-butyldiphenylsilyl cyanide (TBDPSCN) to sterically hindered ketones proceeded in good yield under catalysis by Lewis acids (ZnI2, CH2Cl2, 25 deg C) or bases
Golinski, Miroslaw,Brock, Carolyn P.,Watt, David S.
p. 159 - 164
(2007/10/02)

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Chemical Properties

Boiling Point: 355.6 °C at 760 mmHg
Flash Point:168.9 °C
Density: 1.01 g/cm³
Vapor Pressure: 0.71 psi ( 55 °C)
Refractive Index: n20/D 1.559(lit.)
PSA: 23.79000
LogP: 3.11248

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