INTERMOLECULAR C-H SILYLATION OF UNACTIVATED ARENES
Reaction mixtures for silvlating arene substrates and methods of using such reaction mixtures to silyiate the arene substrates are provided. Exemplary reaction mixtures include the arene substrate, a liganded metal catalyst, a hydrogen acceptor and an organic solvent. The reaction conditions allow for diverse substituents on the arene substrate.
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Paragraph 00131
(2015/03/28)
Mechanism of the rhodium-catalyzed silylation of arene C-H bonds
Mechanistic studies on the rhodium-catalyzed silylation of arene C-H bonds are reported. The resting state of the catalyst was fully characterized by NMR spectroscopy and X-ray diffraction and was determined to be a phosphine-ligated Rh(III) silyl dihydri
Cheng, Chen,Hartwig, John F.
supporting information
p. 12064 - 12072
(2014/10/16)
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