- New, Chiral Silylated Organophosphorus(III) Reagents: Syntheses and Applications in the Asymmetric Phosphorylation of Aldehydes
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The new silylated organophosphorus(III) compounds, (1R,2S)-(O,N-ephedrine)POSiR3 (R3=Ph3, t-BuMe2, Et3) have been synthesised and shown to react with benzaldehyde to afford the phosphonate esters (1R,2S)-(O,N-ephedrine)P(=O)CHPh(OSiR3) with good stereosel
- Sum, Vivienne,Davies, Anita J.,Kee, Terence P.
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p. 1771 - 1773
(2007/10/02)
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