Copper nanoparticles from copper aluminum hydrotalcite: An efficient catalyst for acceptor- and oxidant-free dehydrogenation of amines and alcohols
An efficient and simple process for the preparation of stable nanocopper(0) on alumina [Cu(0)/Al2O3] from the inorganic composite precursor copper aluminum hydrotalcite (Cu-AlHT) by a chemical reduction method is described. Cu(0)/ Al2O3 was employed as an efficient catalyst in the acceptor- and oxidant-free dehydrogenation of various amines and alcohols to their corresponding dehydrogenated products in good to excellent yields. The stability of Cu(0)/Al2O3 was assessed by studying its recoverability and reusability in the dehydrogenation of amines and alcohols for up to five cycles.
Damodara, Dandu,Arundhathi, Racha,Likhar, Pravin R.
supporting information
p. 189 - 198
(2014/03/21)
A CONVENIENT SYNTHESIS OF TRIFLUOROMETHYL SUBSTITUTED PHTHALOCYANINES
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Pawlowski, Georg,Hanack, Michael
p. 351 - 364
(2007/10/02)
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