- Reactions with Phosphororganic Compounds XLVIII. On the Behaviour of cis-1,2-Diols towards TPP/DEAD
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Reaction of the vicinal diols of steroids 1, 5, 7, 10, 13, and 16 with TPP/DEAD yields both regio- and stereospecifically the oxosteroids 2, 6, 8, 11, 14, and 15 by displacement of an axial hydrogen and extrusion of TPPO besides the cholest-4-en-6-ols 9 a
- Penz, Gottfried,Zbiral, Erich
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p. 1045 - 1054
(2007/10/02)
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