Diastereoselectivity in prebiotically relevant 5(4H)-oxazolone-mediated peptide couplings
A stereochemical study of a potentially prebiotic peptide-forming reaction was carried out as the first part of a systems chemistry investigation of potential paths for symmetry breaking. Substantial diastereomeric excesses result from a fast epimerization of the 5(4H)-oxazolone intermediate in aqueous solution. The Royal Society of Chemistry.
Beaufils, Damien,Danger, Gregoire,Boiteau, Laurent,Rossi, Jean-Christophe,Pascal, Robert
p. 3100 - 3102
(2014/03/21)
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