Rate constants for the OH reactions with oxygenated organic compounds in aqueous solution
The kinetics of the oxidation of functionalized organic compounds of atmospheric relevance by the hydroxyl radical (OH) was measured in the aqueous phase. Competition kinetics, using the thiocyanate anion (SCN-) as competitor, was applied using both a las
A Pulse Radiolysis Study of Some Dicarboxylic Acids of the Citric Acid Cycle. The Kinetics and Spectral Properties of the Free Radicals Formed by Reaction with the OH Radical
The reactions between the OH radical and fumaric acid, maleic acid, malic acid and succinic acid were studied using pulse radiolysis techniques.The rates of reaction, the absorption spectra of the resultant free radicals and the rates of disappearance of those radicals were determined as a function of pH over virtually the entire pH range (pH 2 - 14). - Key words: Pulse Radiolysis, Dicarboxylic Acid Radicals
Cabelli, Diane, E.,Bielski, Benon H. J.
p. 1731 - 1737
(2007/10/02)
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