cas 160598-92-5, Villosin | Articles data ｜lookchem

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160598-92-5

Articles about 160598-92-5Total 3 be found

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Expedient synthesis of villosin and its isomer (E)-labda-8(17),12,14-trien-15(16)-olide
The synthesis of the title compounds has been achieved in concise, highly regiocontrolled fashion from commercially available (+)-sclareolide. In addition, we offer evidence that the structure of a newly reported natural product from Zingiber ottensii is incorrect.
Boukouvalas, John,Wang, Jian-Xin,Marion, Olivier
p. 7747 - 7750
(2007)
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Lewis Acid-Catalyzed Stereoselective α-Addition of Chiral Aldehydes to Cyclic Dienol Silanes: Aqueous Synthesis of Chiral Butenolides
The stereoselective α-addition to cyclic dienol silanes has rarely been exploited, in contrast to the well-studied γ-addition of conjugated butenolides. In this study, an unprecedent catalytic Mukaiyama aldol α-addition of 2-trimetylsiloxy furan to optically pure aldehydes in water-containing solvents is reported. The synthetic utility of this concept was demonstrated in the efficient synthesis of six bioactive natural products: vitexolide D, curcucomosin C, villosin, chinensine C, (+)-coronarin E and (E)-labda-7,11,13-trien-16,15-olid.
Adamkiewicz, Anna,W?glarz, Izabela,Butkiewicz, Aleksandra,Woyciechowska, Marta,Mlynarski, Jacek
p. 667 - 678
(2019/12/24)

Synthesis of chinensines A-E
(Chemical Equation Presented) Short and efficient syntheses of coronarin E (4) and chinensines A-E (5-9) have been accomplished. The use of two different types of reaction of singlet oxygen (1O2) lies at the heart of the synthetic st
Margaros, Ioannis,Vassilikogiannakis, Georgios
p. 4826 - 4831
(2008/02/05)

More Articles about upstream products of 160598-92-5

More Articles about downstream products of 160598-92-5

117591-81-8
[(5S,9S,10S)-11(E)]-15,16-epoxy-8⁽¹⁷⁾,11,13,⁽¹⁶⁾14-labdatetraene

Chemical Properties

Melting Point: 124-125 °C
Boiling Point: 431.2±24.0 °C(Predicted)
Density: 1.04±0.1 g/cm3(Predicted)
PSA: 26.30000
LogP: 4.82460

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