Palladium catalyzed intramolecular acylcyanation of alkenes using α-iminonitriles
Reported here is a palladium catalyzed intramolecular acylcyanation of alkenes using α-iminonitriles. Through this method, highly functionalized indanones are synthesized in moderate to high yields using Pd(PPh 3)4, without need for any additional ligands, and a common Lewis acid (ZnCl2). Additionally, the reaction tolerates substitution at various positions on the aromatic ring including electron donating and electron withdrawing groups. This journal is the Partner Organisations 2014.
Rondla, Naveen R.,Ogilvie, Jodi M.,Pan, Zhongda,Douglas, Christopher J.
p. 8974 - 8977
(2014/08/05)
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