3-Nitropyridine was reacted with ammonia or alkylamines and KMnO4 under several different conditions. Substitutions in the para position to the nitro group were obtained with high regioselectivity: with ammonia, 2-amino-5-nitropyridine (66%), w
Bakke, Jan M,Svensen, Harald
p. 4393 - 4395
(2007/10/03)
Synthesis of 3,4-diaminopyridine and imidazo[4,5-c]pyridines by nitration of 4-acylaminopyridines
New methods for the preparation of 3,4-diaminopyridine (5) and imidazo[4,5-c]pyridines 7a,7b based on direct nitration of 4- acylaminopyridines 3a, 3b have been explored.
Bakke,Riha
p. 1143 - 1145
(2007/10/03)
Regioselectivity of the Amination of Some 3-Nitropyridines by Liquid Ammonia / Potassium Permanganate
3-Nitropyridine and some of its derivatives are aminated in a liquid ammonia solution of potassium permanganate to the corresponding 2- and (or) 4- and (or) 6-amino compounds.Quantumchemical calculations for a few 3-nitropyridines suggest that the experimentally observed regioselectivity of the amination is controlled by Coulombic interaction. --- Key Words: Amination / Nitropyridines / Reactivity indices / Calculations, MNDO
Wozniak, Marian,Baranski, Andrzej,Szpakiewicz, Barbara
p. 875 - 878
(2007/10/02)
Some new methods for preparing 2,3- and 3,4-diaminopyridines
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Campbell,Greene,Lavagnino,et al.
p. 669 - 672
(2007/10/02)
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