THE INFLUENCE OF HYDROGEN BONDING ON THE SOLVOLYTIC REACTIVITY OF NICOTINATES IN FLUORINATED ALCOHOLS
A systematic investigation of solvolytic reactivities of allylic and benzylic nicotinates and their N-methylated derivatives in 80percent EtOH, 97percent TFE and 97percent HFIP was undertaken.The nicotinates in 97percent HFIP are slightly more reactive th
Jursic, Branko,Sunko, Dionis E.,Ladika, Mladen
p. 4367 - 4376
(2007/10/02)
Solvolysis of 2-Alkenyl-2-cyclohexenyl p-Nitrobenzoates
In an attempt to study possible ?-participation in allyl derivatives, 2-alkenyl-3-methyl-2-cyclohexenyl p-nitrobenzoates 6 and 7 were solvolyzed in 97 wt percent trifluoroethanol and 80 vol percent ethanol.These esters show in both solvents a solvolysis r
Ladika, Mladen,Sunko, Dionis E.
p. 4544 - 4548
(2007/10/02)
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