Synthesis of functionally substituted sulfides by alkylation of electrochemically generated thiolate on platinum or glassy carbon cathodes with organohalides of various structures is reported.
Petrosyan, V. A.,Niyazymbetov, M. E.,Konyushkin, L. D.,Litvinov, V. P.
ELECTROCHEMICAL SYNTHESIS OF FUNCTIONALLY SUBSTITUTED SULFIDES
A method of synthesis of functionally substituted sulfides by cathode electrolysis of thiols on platinum or carbon glass electrodes in the presence of organyl halides was developed.The method of the rotating disk electrode with ring showed that this process passes through the intermediate formation of a thiolate anion on the cathode, and its reaction with the organyl halide results in a high yield of sulfides.
Niyazymbetov, M. E.,Petrosyan, V. A.,Konyushkin, L. D.,Litvinov, V. P.
Ruthenium-catalyzed rearrangement of propargyl sulfoxides: Formation of α,β-unsaturated thioesters
Our previously developed strategy of generating ketene intermediates via Ru-catalyzed intramolecular oxidation of terminal alkynes is applied to propargyl sulfoxides. The reaction undergoes interesting further rearrangement upon the ketene generation to a
Zheng, Renhua,Wang, Youliang,Zhang, Liming
supporting information
p. 3144 - 3146
(2015/06/02)
More Articles about upstream products of 17277-57-5