Iodide-Catalyzed Synthesis of Secondary Thiocarbamates from Isocyanides and Thiosulfonates
A new method for the synthesis of secondary thiocarbamates from readily available isocyanides and thiosulfonates with broad functional group tolerance is reported. The reaction proceeds under mild reaction conditions in isopropanol and is catalyzed by inexpensive sodium iodide.
Mampuys, Pieter,Zhu, Yanping,Sergeyev, Sergey,Ruijter, Eelco,Orru, Romano V. A.,Van Doorslaer, Sabine,Maes, Bert U. W.
p. 2808 - 2811
(2016/07/06)
Kinetics and mechanism of the aminolysis of aryl N-isopropyl thiocarbamates in acetonitrile
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Oh, Hyuck Keun
experimental part
p. 4095 - 4098
(2012/03/22)
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