- Liquid crystal behavior, photoluminescence and gas sensing: A new series of ionic liquid crystal imidazole and benzoimidazole bearing chalcone groups, synthesis and characterization
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Four new series of chalcones containing imidazole bromonium and benzimidazole bromonium salts with spacer alkyl chains (Cn, n = 2 and 4) were synthesized and the chemical structure, thermal behavior, photoluminescence and gas sensing were characterized by
- Abbas, Wahaj Raed,Mohammad, Abdulkarim-Talaq
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p. 38444 - 38456
(2021/12/20)
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- Luminescent mesogenic borondifluoride complexes with the Schiff bases containing salicylideneamines and β-enaminoketones core systems
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Three new families of borondifluoride complexes 1a–c derived from salicylideneamines 2a and β-enaminoketonates 2b–c were reported, and their mesomorphic and optical properties were also investigated. One single crystal and molecular structure of nonmesogenic BF2 complex 1c (n = 10) was resolved and the geometry of the central boron atom was tetrahedron. A larger dihedral angle of 81.3° between the two phenyl rings observed in crystal lattice was attributed to the lack of liquid crystallinity. Boron complexes 1a formed monotropic SmA phases, while boron complexes 1b exhibited enantiotropic SmC mesophases. The optical property of the boron complexes was dependent on their molecular structures, and they emitted a blue–to–green emission at λmax = 476–541 nm in the solution and 488–550 nm in the solid state. This is the first group of mesogenic BF2 complexes with the Schiff bases derived from respective salicylideneamines and β-enaminoketones.
- Lei, Zih-Yang,Lee, Gene-Hsiang,Lai, Chung K.
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- Design, synthesis, and discovery of 5-((1,3-diphenyl-1H-pyrazol-4-yl)methylene)pyrimidine-2,4,6(1H,3H,5H)-triones and related derivatives as novel inhibitors of mPGES-1
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Human mPGES-1 has emerged as a promising target in exploring a next generation of anti-inflammatory drugs, as selective mPGES-1 inhibitors are expected to discriminatively suppress the production of induced PGE2 without blocking the normal biosynthesis of other prostanoids including homeostatic PGE2. Therefore, this therapeutic approach is believed to reduce the adverse effects associated with the application of traditional non-steroidal anti-inflammatory drugs (tNSAIDs) and selective COX-2 inhibitors (coxibs). Identified from structure-based virtue screening, the compound with (Z)-5-benzylidene-2-iminothiazolidin-4-one scaffold was used as lead in rational design of novel inhibitors. Besides, we further designed, synthesized, and evaluated 5-((1,3-diphenyl-1H-pyrazol-4-yl)methylene)pyrimidine-2,4,6(1H,3H,5H)-triones and structurally related derivatives for their in vitro inhibitory activities. According to in vitro activity assays, a number of these compounds were capable of inhibiting human mPGES-1, with the desirable selectivity for mPGES-1 over COX isozymes.
- Ding, Kai,Zhou, Ziyuan,Zhou, Shuo,Yuan, Yaxia,Kim, Kyungbo,Zhang, Ting,Zheng, Xirong,Zheng, Fang,Zhan, Chang-Guo
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p. 858 - 862
(2018/02/21)
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- Synthesis and liquid crystalline properties of a new homologous series of 4,5-disubstituted 2H-[1,2,3]-triazoles via azide-chalcone oxidative cycloaddition reaction
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A new homologous series of 4,5-disubstituted 2H-[1,2,3]-triazole derivatives were synthesized from chalcones and sodium azide via oxidative cycloaddition reaction; CuI was used as catalyst. Flexibility in the synthesized molecules was provided by attaching straight alkoxy chains. The synthesized compounds were characterized by elemental analysis, and 1HNMRand 13CNMRand LC-MS spectroscopies . The stability and range of the mesophases increased with the length of the chain on the triazoles. The melting point, transition temperatures, and enantiotropic liquid crystal morphologies were determined by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM) equipped with a hot stage. Journal compilation
- Sowmya,Rai, K. M. Lokanatha
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p. 764 - 768
(2017/07/07)
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- Fluorescent columnar bis(boron difluoride) complexes derived from tetraketonates
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Three new series of bis-(boron difluoride) complexes 1a-c derived from substituted tetraketonates 2a-c are reported, and their mesomorphic and optical properties have been investigated. Two single crystals of mesogenic ligand 2a (n = 6) and nonmesogenic d
- Chen, Ya-Wen,Lin, Yen-Chun,Kuo, Hsiu-Ming,Lai, Chung K.
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p. 5465 - 5477
(2017/07/10)
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- Synthesis, characterization and study of liquid crystal properties of new homologous chalcone series
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Onenewmesogenic homologous series of chalconyl derivativewith two ring (3/-(4/- (decyloxy) phenyl-1-(4-(alkoxy) phenyl) prop-2-en-1-one) has been synthesized and characterized by a combination of elemental analysis and standard spectroscopic methods. In the series, the lower members (C4 and C5) exhibit only enantiotropic nematic mesophase but middle and higher members exhibit enantiotropic nematic as well as smecticmesophase. The nematicmesophase commence from C4 homologue and smectic mesophase (smectic-A type texture) commence from C6 homologue as enantiotropic and persists up to the lastmember synthesized. The mesomorphic properties of present serieswere compared with other two structurally similar series to study the effects of change of meta and para position on the mesomorphism.
- Jain,Patel
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- Synthesis and antimicrobial studies of hydroxylated chalcone derivatives with variable chain length
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A series of (E)-1-(4-alkyloxyphenyl)-3-(hydroxyphenyl)-prop-2-en-1-one have been successfully synthesised via Claisen-Schmidt condensation. The synthesised chalcone derivatives consisted of hydroxyl groups at either ortho, meta or para position and differed in the length of the alkyl groups, CnH 2n+1, where n=6, 10, 12 and 14. The structures of all compounds were defined by elemental analysis, IR, 1H- and 13C-NMR. The antimicrobial studies were carried out against wild-type Escherichia coli American Type Culture Collection 8739 to evaluate the effect of the hydroxyl and the alkyl groups of the synthesised chalcones. All the synthesised compounds have shown significant antimicrobial activities. The optimum inhibition was dependent on the position of the hydroxyl group as well as the length of the alkyl chains.
- Ngaini, Zainab,Haris Fadzillah, Siti M.,Hussain, Hasnain
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experimental part
p. 892 - 902
(2012/08/28)
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- Synthesis and characterization of chalconesubstituted phosphazenes
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A series of mono[(E)-1-(4-alkyloxyphenyl)-3-(4-hydroxy-phenyl)prop-2-en-1- one]cyclotriphosphazenes and hexakis[(E)-1-(4-alkyloxy-phenyl)-3-(4-hydroxy- phenyl) prop-2-en-1-one]cylotriphosphazenes have been synthesized. A convenient synthetic method was pe
- Ngaini, Zainab,Rahman, Norashikin I. Abdul
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experimental part
p. 654 - 658
(2010/08/21)
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- Supramolecular metallomesogens. Self-organization of an H-bonded tetrameric assembly into columnar phase from single component
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The first example of supramolecular metallomesogens derived from palladium complexes exhibiting columnar phase is reported, and the formation of the mesophase is induced by H-bonding in a tetrameric assembly. The Royal Society of Chemistry.
- Wang, Yueh-Ju,Song, Jian-Hong,Lin, Yu-Siang,Lin, Ching,Sheu, Hwo-Shuenn,Lee, Gene-Hsiang,Lai, Chung K.
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p. 4912 - 4914
(2007/10/03)
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- Precursors for fragrant ketones and fragrant aldehydes
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The present invention refers to fragrance precursors of formula I for a fragrant ketone of formula II and one or more fragrant aldehydes or ketones of formula III and IV, These fragrance precursors are useful in perfumery, especially in the fine and functional perfumery.
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- Quinoxaline compound, liquid crystal composition containing the compound, liquid crystal device using the composition, display apparatus and display method
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A quinoxaline compound of the formula (I) according to claim 1 characterized by having at least one quinoxaline-2,6 (or 2,7)-diyl group is suitable as a component for a liquid crystal composition providing improved response characteristics and a high contrast. A liquid crystal device is constituted by disposing the liquid crystal composition between a pair of electrode plates. The liquid crystal device is used as a display panel constituting a display apparatus providing good display characteristics.
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- Preparation and Coupling Reactions of Alkynyl(phenyl)iodonium Salts Bearing Long Alkoxy Chains. Formation of Liquid-Crystalline Diacetylenes
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Alkynyl(phenyl)iodonium tosylates with long alkoxy chains, such as (octyloxy)-, (decyloxy)-, (dodecyloxy)-, and (tetradecyloxy)phenyl, were prepared by reaction of the corresponding alkynes with hydroxy(tosyloxy)iodobenzene.The alkynyliodonium tosylates w
- Kitamura, Tsugio,Lee, Chi Han,Taniguchi, Hiroshi,Matsumoto, Masaru,Sano, Youich
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p. 8053 - 8057
(2007/10/02)
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- Novel liquid crystal compounds, derivatives of 2-pyrone
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6-(4-n-Hexyloxyphenyl)- and 6-(4-n-decyloxyphenyl)-2-pyrones, which possess smectic and nematic mesomerphism, were synthesized. - Key words: acetophenone alkoxy-derivatives, 5-(alkoxyphenyl)-1,1-dichloropenta-1,3-dien-2-ones, 6-(4-n-alkoxyphenyl)-2-pyrone
- Zakharkin, L. I.,Sokolovskaya, S. V.,Moldovanova, L. K.,Guseva, V. V.
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p. 1698 - 1699
(2007/10/02)
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- Functionalized 1,1-Ethene Dithiolates as Ligands, II. Nickel(II), Palladium(II) and Platinum(II) Complexes of Substituted β-Keto Dithio Acid Dianions
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para-Substituted β-ketodithiocinnamic acid dianions react with L2MCl2 to give the 1,1-ethene dithiolate complexes L2M (3: M = Ni, L = PBu3, n = 12; 4a,b: M = Pd, L = PPh3, n = 1, 8; 5a: M = Pt, L = PEt3, n = 1; 5b, 5e-g; 5i: M = Pt, L = PPh3, n = 1, 8, 10, 12, 14; 5c,h: M = Pt, L = 1/2 dppe, n = 1, 12; 5j: M = Pt, L = PPh2Tol, n = 12; 6a-c: M = Pt, L = 1/2 dmphen, n = 8, 12, 16); L2Pt (7a,b: L = PPh3, 1/2 dmphen),(Ph3P)2Pt (8) and L2M (9a: M = Pd, L = PPh3; 9b: M = Pt, L = PEt3; 9c: M = Pt, L = PPh3, 9d: M = Pt, L = 1/2 dppe).These compounds have been characterized by their UV, IR, (1)H, (13)C and (31)P NMR spectra.
- Weigand, Wolfgang,Saumweber, Rupert,Schulz, Peter
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p. 1080 - 1088
(2007/10/02)
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- Synthesis and Properties of Thermotropic Liquid Crystals with Two Non-Mesogenic Units and a Flexible Central Spacer
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The synthesis of new di-Schiff bases with two non-mesogenic units and a flexible central spacer (-CH2-CH2-) in their structure is reported.The mesomorphic properties of the compounds were investigated by differential scanning calorimetry (DSC) and polariz
- Cerrada, P.,Marcos, M.,Serrano, J. L.
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