Alternative Ligands, XIV. - Novel Chelating Ligands of the Type (2-Me2E'C6H4)Si(EMe2)Me2 (E, E' = N, P, As; Me = CH3)
Chelating ligands of the type (2-Me2NC6H4)Si(EMe2)Me2 (E = N, P, As) are prepared by ortho-lithiation of N,N-dimethylaniline followed by reaction with ClSi(NMe2)Me2 to yield (2-Me2NC6H4)Si(NMe2)Me2.Cleavage of the SiN-bond with MePCl2 affords (2-Me2NC6H4)
Aslanidis, Paraskevas,Grobe, Joseph
p. 280 - 288
(2007/10/02)
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