Abstract (Chloromethyl)dimethylsilanol was synthesized by the hydrolysis of (chloromethyl)dimethylchlorosilane, N-[(chloromethyl)dimethylsilyl]amines, or N-(chloromethyl)dimethylsilyl-N-methylamide of diisopropylphosphoric acid. Graphical abstract: [Figure not available: see fulltext.]
PH DEPENDENCE OF HYDROLYTIC REMOVAL OF SILYL GROUP FROM TRIALKYLSILYL ETHERS
Rate constants for the acid and base-catalyzed hydrolysis of the trialkylsilyl ethers of alcohols were quantitatively correlated with Taft's ?* and Es values of the substituens on Si and O atoms of the ether linkage.The regression equations for kH and kOH were satisfactorily computed.
Shirai, Naohiro,Moriya, Kiyoshi,Kawazoe, Yutaka
p. 2211 - 2214
(2007/10/02)
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